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Nintendo Switch Online is continuing to expand in exciting new ways, this time with Crash Team Racing: Nitro-Fueled. For a limited time, Nintendo Switch Online members will be able to trial the full version of Crash Team Racing: Nitro-Fueled, which includes local and online play.
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The trial run begins on December 30 at 11:00 AM PT and will run until January 5 at 11:59 PM PT. Players who are interested will want to take advantage of playing Crash Team Racing: Nitro-Fueled during this time. Of course, Nintendo Switch Online players are used to enjoying free content for limited periods, as its Game Trials program has made full games like Overwatch temporarily available for free on the Nintendo Switch. It's likely that free trials like these will continue to be a thing moving forward, as Nintendo tries to sweeten its online deal.
The road is going to burn in winter. Crash Team Racing Nitro-Fueled, the reimagining of the classic from the first PlayStation, has returned from Activision and Beenox in a game that respects its legacy, although it adds many new features compared to the original version. If you have not tried it and you are a subscriber of Nintendo Switch Online, you will have the possibility to access the full version for free. Of course, only for a limited time.
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The next Game Trial has been revealed for the Nintendo Switch Online service. In just a couple of days, members can try out the full game for an entire week, including local and online multiplayer. Save data will transfer to the full version.
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According to Pepsi's VP of marketing, Todd Kaplan, "Some people still cite heavy carbonation as a barrier to enjoying an ice-cold cola." Given that knowledge, Pepsi endeavored to "redefine cola" (their words) by creating a version of their cola that was smoother and creamier, using the same nitrogen technology that's been all the rage with cold brew coffee and beer in recent years.
Manuscript id: Peer J -23415Title: One-pot multicomponent nitro-Mannich reaction using a heterogeneous catalyst under solvent-free conditionsAuthors: Giovanna Bosica and Ramon ZammitAn environmentally-friendly, one-pot multicomponent reaction of various aldehydes, amines and nitroalkanes for the synthesis of β-nitroamines is described using Amberlyst A-21 supported CuI catalyst.The Ms can be accepted for publication after minor revision. 1.One of the minor problems of this manuscript is English, which needs through editing. 2. Delete Fig 2. as advantages are summarized in conclusion.
The article generally meets the standards for being published in PeerJ. However, there is one experiment that should be carried out and reported to fully support the statement that the catalyst is truly heterogeneous. Indeed, the only way to acertain that the catalytic activity is strictly and solely the effect of the solid (and not for example from the 1% Cu that is leaching) is to perform a "hot filtration test". The reaction should be stopped at an early stage, when conversion has started but did not reach high values. Then the catalyst is removed (e.g. by filtration) and the filtrate is further allowed to react in the exact same conditions. If conversion value do not evolve at all, then the heterogeneous nature of the catalysis is confirmed. When mechanistic insights are provided, it is not always clear what is speculation and what is known from the litterature (e.g. 153-155). In the latter case, a reference would be needed.
Comments for the authorsThe authors describe an environmentally-friendly one pot multicomponent reaction of aldehydes, amines and nitroalkanes using the Amberlyst A-21 supported copper (I) iodide. The present nitro-Mannich type reaction tolerated versatile aldehydes and amines and regioselectively afforded the beta-nitroaminoalkanes in high yields. Furthermore, the reaction was achieved in a solvent-free condition. The authors also show the environmental acceptability of the nitro-Mannich reaction by calculating both the atom economy and the E-factor (as shown in eq 1 and 2). The catalyst seems to be practical and useful according to the investigation of Table 8 (Comparison of E-factore of the catalytic systems) and Table 9 (which shows the percentage of copper ions that leached into the solution from the heterogeneous catalyst). The manuscript seems to be suitable for the article of the PeerJ after minor revisions.1)Text: line 33: synthesis via umpolung chemistry ----- synthesis of umpolung chemistry2)Experimental Section: please check the 1H NMR.4e: 1H NMR: 2H is missing.4g: 1H NMR: 1H is too much.4j: 1H NMR: 1H is too much.4k: 1H NMR: 2H is missing.3)The authors should cite the reference on the Aza-Henry reaction of nitriles with copper iodide/cesium carbonate/DBU in nitromethane (Org. Lett. 2018, 20, 1130).
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